Abstract
The one-dimensional copper(II) coordination polymers [Cu(tdpd)(pda)] n ( 1 ) (H 2 tdpd=1,4,5,6-tetrahydro-5,6-dioxo-2,3-pyrazinedicarbonitrile, pda=1,2-phenylenediamine) has been synthesized and characterized. Compund 1 is a linear chain of copper(II) ions bridged by tdpd 2− dianion with terminal pda ligand. Magnetic susceptibility measurement shows antiferromagnetic couplings between the copper(II)ions.
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