Abstract
The crystal and molecular structures of [Ni(Im)6](dtp)2 (Im = imidazole, dtp = O,O′-diphenyldithiophosphate) have been determined by X-ray crystallography. It crystallizes in the triclinic system, space group Pī, with cell parameters a = 9.375 (2), b = 12.324(3), c = 13.285(3) Å, α = 107.86(3), β = 102.28(3), γ = 109.24(3), and Z = 1. The crystal structure of the title compound is built up of discrete monomeric molecules of [Ni(Im)6](dtp)2. The nickel (II) ion is hexacoordinated by six imidazole molecules and the coordination environment of Ni (II) is of octahedral geometry. In the solid state, a network of N-H∙∙∙S intermolecular hydrogen bonds connect the Ni(Im)6 moieties and O,O′-diphenyl- dithiophosphate molecules, forming a three-dimensional structure.
Highlights
The nickel (II) ion is hexacoordinated by six imidazole molecules and the coordination environment of Ni (II) is of octahedral geometry
Imidazole is of considerable interest as a ligand in that its presence in many biological systems provides a potential binding site for metal ions [1, 2]
We describe the synthesis, and crystal structure of the title compound, hexakis(imidazole) nickel (II) O,O′diphenyldithiophosphate, [Ni(Im)6](Ph2O2PS2)2
Summary
Imidazole is of considerable interest as a ligand in that its presence in many biological systems provides a potential binding site for metal ions [1, 2]. Abstract: The crystal and molecular structures of [Ni(Im)6](dtp)2 (Im = imidazole, dtp = O,O′-diphenyldithiophosphate) have been determined by X-ray crystallography. The crystal structure of the title compound is built up of discrete monomeric molecules of [Ni(Im)6](dtp)2. The nickel (II) ion is hexacoordinated by six imidazole molecules and the coordination environment of Ni (II) is of octahedral geometry.
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