Abstract
A new complex compound [Mg(H2O)6]Br2 · 18-crown-6 · 2H2O(I) is synthesized, and its structure is studied by X-ray diffraction analysis. The crystals are monoclinic: space group P21/c, a = 7.128 A, b = 18.584 A, c = 9.598 A, A = 103.01°, Z = 2; R = 0.039 for 2180 independent reflections (CAD-4 automated diffractometer, λMoKα radiation). The coordination polyhedron of the Mg2+ cation is a slightly distorted octahedron. The 18-crown-6 molecule has the conformation of a distorted crown with the approximate D3d symmetry. The crystal contains a branched three-dimensional network of intermolecular (interionic) hydrogen bonds.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
