Abstract
The complex [Zn(pbp) 2](ClO 4) 2 [pbp=N-(1-(2-pyrid-2-yl)benzoylidene)1,3propanediamine] was obtained by reaction of 2-benzoylpyridine and 1,3-propane diamine with zinc perchlorate in ethanol. A single crystal X-ray study shows that the complex is monomeric with the zinc atom coordinated by six nitrogen atoms from two singly neutral tridentate ligands to form a distorted octahedral geometry. The Zn—N bond lengths range from 2.070(5) to 2.123(6) Å.
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