Abstract
Reaction of the bidentate ligand (HL) generated from condensation of acetylferrocene and S-benzyldithiocarbazate with nickel chloride hexahydrate afforded a new nickel complex Ni(HL)2Cl2. Both compounds have been characterized by elemental analyses, 1H NMR, IR and UV spectroscopies. Single-crystal X-ray analysis of the complex indicates that HL as a neutral bidentate ligand coordinates to the nickel atom via the imine nitrogen and thione sulfur atoms and the coordination geometry of the central metal is tetrahedral.
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