Abstract

A new organic compound with the formula C39H46Cl2N6O was synthesized from aqueous solution of 4,4′-diaminodiphenylmethane and hydrochloric acid at room temperature. This compound crystallizes in the monoclinic space group C2: a = 25.6525(16), b = 5.7107(3), c = 13.7777(8) A, β = 118.862(2)°, V = 1767.64(22) A3 and Z = 2, giving D x = 1.288 g cm−3. The refinement converged to R 1 = 0.027 and wR 2 = 0.0649. The structural arrangement can be described as infinite layers parallel to bc plane. In these layers cations and non protonated molecules are linked with N-H...N hydrogen bonds building [C39H44N6]2+ organic clusters. These clusters, in turn, are linked by N-H...Cl and O-H...Cl hydrogen bonds.

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