Synthesis and crystal structure of a new copper(II) binuclear complex bridged by the reduced derivative of a nitronyl nitroxide biradical

Abstract

A new copper(II) binuclear complex, [Cu(hfac)2]2(IMH)2Ph(OMe)2 ((IMH)2Ph(OMe)2 = 2,5-dimethoxyl-1,4-bis(4′,4′,5′,5′-tetramethylimidazoline-3′-oxide)benzene, hfac = hexafluoroacetonate), bridged by a reduced derivative of a nitronyl nitroxide biradical has been synthesized and characterized by X-ray crystallography. The complex crystallizes in the monoclinic space group P21/n, with a = 10.002(14), b = 19.950(3), c = 14.504(2) Å, β = 108.842(3)° and Z = 2. The structure refined to a final R value of 0.0644. The complex contains two copper(II) ions bridged by a reduced derivative of a nitronyl nitroxide biradical with a Cu ··· Cu separation of 8.430(2) Å.