Abstract

The binuclear zinc(II) complex [Zn 2L(O 2CCH 3) 2] · CH 3CCH 2OOH was synthesized by a template reaction in alcohol. The crystal and molecular structure of this complex has been determined by X-ray analysis. The binucleating ligand L, 2,6-diformylpyridine TV-oxide bis(benzoylhydrazone), is in doubly deprotonated form. All the coordinated atoms in the bis-Schiff base ligand and two zinc atoms in the complex molecule are coplanar, and the N-oxide oxygen atom bridges two zinc atoms with the same bond length of 2.24(1) Å. The two acetate ions act as bidentate ligands linking two zinc atoms, both being in a distorted trigonal-bipyramidal environment.

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