Abstract
The isolation of stable carbenes of the Arduengo (1a) and Wanzlick (2a) type has prompted us to look for stable nitrenium ions of the related structural type 1-methyl-3-(4-nitrophenyl)-1,2,3 triazolium perchlorate (6). The title compound (C9 H11 Cl N4 O6) was isolated and structure was investigated by X-ray crystallography. It crystallizes in the monoclinic space group P21/c with cell parameters a=9.704(1) Å, b=12.580(2) Å, c=13.684(8) Å, Z=4. The molecules appear to be stacked.
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