Abstract
Synthesis and crystal structure of 1,6-Bis-(N,N-diethylaminothiocarbamoylimino)-1,6-diphenyl-2,5-dithiahexane are reported as well as those of its dimeric AgI complex (as monotoluene adduct of the diperchlorate) and its tetrameric μ-tetrabromo AgI complex. Synthese und Kristallstruktur von 1,6-Bis(N,N-diethylthiocarbamoylimino)1,6-diphenyl-2.5-dithiahexan, seinem dimeren AgI-Komplex [Ag2(C26H34N4S4)2](ClO4)2 · C7H8 und seinem tetrameren μ-Tetrabromo-AgI-Komplex [Ag4(C26H34N4S4)2Br4] Die Synthese und Rontgenstrukturanalyse des potentiell vierzahnigen Schwefel-Chelatliganden 1,6-Bis-(N,N-diethylthiocarbamoylimino)-1,6-diphenyl-2,5-dithiahexan und seines dimeren 1 : 1 Silber(I)-Komplexes (als Diperchlorat) sowie seines tetrameren 1/2 : 1 : 1 Silber-Bromokomplexes werden beschrieben.
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