Synthesis and Corrosion Inhibition Performance of Mannich Bases on Mild Steel in Lactic Acid Media.

Abstract

Heterocyclic Mannich bases, N-(3-oxo-3-phenylpro-pyl)thiazol-2-aminium chloride (DTZA) and N-(3-oxo-3-phenylpropyl)-1H-pyrazol-3-aminium chloride (DPZA), were developed for the corrosion inhibition of N80 steel in a 15 wt % lactic acid solution. Weight loss measurements, electrochemical techniques, surface characterization, and theoretical calculations were combined to investigate their anticorrosion performance and mechanism. The results showed that DTZA exhibited a satisfactory inhibitor efficiency of 97.56% with a dosage of 0.15% at 363 K, while DPZA achieved only 58.3% under the same conditions. Adsorptions of both inhibitors on the metal surface followed the Langmuir model with physical and chemical adsorptions. Based on X-ray photoelectronic spectroscopy (XPS) analysis, DFT calculations, and molecular dynamics (MD) simulations, stronger interactions between DTZA and iron than those in the case of DPZA were revealed, leading to the formation of a compact protective film on the metal surface, which is attributed to the presence of a thiazole ring in the DTZA chemical structure.