Synthesis and conversions of metallocycles. 7. A novel approach to the synthesis of 3,4-dialkyl-substituted aluminacyclopentanes in the presence of Cp2ZrCl2

U M Dzhemilev,A B Morozov,G A Tolstikov,A G Ibragimov,R R Muslukhov

doi:10.1007/bf00961245

Synthesis and conversions of metallocycles. 7. A novel approach to the synthesis of 3,4-dialkyl-substituted aluminacyclopentanes in the presence of Cp2ZrCl2

U M Dzhemilev, A B Morozov + Show 3 more

https://doi.org/10.1007/bf00961245

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Journal: Bulletin of the Academy of Sciences of the USSR, Division of chemical science	Publication Date: Jul 1, 1991
Citations: 6

#Presence Of Cp2ZrCl2 #Metallic Magnesium + Show 4 more

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Abstract

A novel approach was developed for the stereoselective synthesis of trans-3,4-dialkyl-substituted aluminacyclopentanes from α-olefins, metallic magnesium, and EtAlCl2 in the presence of catalytic amounts of Cp2ZrCl2. The hydrolysis and deuterolysis products of the 3,4-dialkyl-substituted aluminacyclopentanes obtained are only in the trans configuration.

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