Abstract

Carboxymethyl cellulose (CMC)/Polyvinyl alcohol (PVA) blend films were prepared by solution casting method. Then, these films were irradiated with γ-rays from a Co-60 source at doses over the range 0–70kGy to investigate the modifications induced in the optical and dielectric properties. The dielectric constant (ε′) was measured in the temperature range 303–408K and in the frequency range 10kHz–1MHz. The indirect optical band gap was found to increase within the dose range 0–10kGy, and to decrease at the higher doses. The refractive index values, however, showed a reversed behavior. The highest transmittance percentage was obtained at 10kGy dose. According to the frequency and temperature dependence of ε′, α- relaxation peaks were observed in all samples and assigned to the micro-Brownian motion of the blend chains. The values of ɛ′ showed a decrease in the dose range 0–10kGy and an increase in the dose range 10–70kGy. The ac conductivity σac (T) showed an Arrhenius type behavior separated into two distinct regions. The results of the present system are compared with those of similar materials.

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