Abstract
Vanadium trichloride reacts with O,O‐dialkyl and alkylene dithiophosphoric acids in 1:3 molar ratio in refluxing benzene to yield V[S2P(OR)2]3, where R=Me, Et, Pr‐n, Pr‐i, Bu‐i and Ph and , where G=–CMe2CMe2–, –CH2CMe2CH2– and –CH2CEt2CH2–. These complexes are semi‐solids or solids and are soluble in common organic solvents. Elemental analyses, molecular weight determinations, IR, NMR spectra (1H, 13C and 31P NMR) and magnetic susceptibilities indicate a hexa–coordinated octahedral structure.
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More From: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
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