Abstract
AbstractReactions of (NBu4)[ReOCl4] with N‐(N″,N″‐dialkylaminothiocarbonyl)‐N′‐(2‐hydroxyphenyl)benzamidines (H2L1) give complexes of the compositions [ReOCl(L1)] (1), cis‐[ReO(L1)(OMe)] (2), or cis,cis‐[{ReO(L1)}2O] (3) depending on the conditions applied. Compound 3 contains a bridging oxygen atom in the cis position to the terminal oxido ligands of both rhenium atoms. The analogous dimeric, sulfur‐bridged compound [{ReO(L1)}2S] (4) was obtained by the reaction of 1 with Na2S.
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