Abstract
Reactions of (Ph3P)3RuCl2 with the ammonium salt of alkylene dithiophosphoric acids in 1:1 and 1:2 stoichiometry gave complexes of the type (Ph3P)3Ru(Cl)[S2POGO](A) and (Ph3P)3 Ru[S2 POGO]2(B), G= -CMe2CMe2-,-CH2CMe2CH2-, -CH2CEt2CH2- and -CMe2CH2CHMe-. Molecular weight determinations and IR and NMR (1H and 31P) spectral data indicate a hexacoordinated octahedral structure. The dithioligand in (B) complexes show monodentate and bidentare chelating.
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