Abstract
: Manganese(II) acetate tetrahydrate reacts with N-(2-hydroxy-1-naphthylidene)glycine (ohglH 2 ) in methanolic solution in (1 : 3.5) molar ratio yielding the complex, tris[N-(2-oxo-1-naphthylidene)glycinato]manganese(III), [Mn III (ohglH) 3 ] and its reaction with other oxygen, nitrogen and/or sulphur donors results in the Mn III complexes having compositions [Mn III (ohgl)(L)(X)] [L = salicylate (sal), X = H 2 O, pyridine (py); 4-nicotinate (nic), X = H 2 O] and [Mn III (ohgl)(ohdtb)(Y)2].H 2 O [ohdtb = o-hydroxydithiobenzoate, Y = H 2 O, py, 3-picoline (3-pic)]. The complexes have been characterized by elemental analysis, molar conductance, magnetic moment, cyclic voltammetry, NMR, electronic and infrared spectral studies. On the basis of UV, IR and NMR spectral evidences, the ligand, N-(2-hydroxy-1-naphthylidene)glycine, exists predominantely in the quinoneamine form and acts as monobasic bidentate and dibasic tridentate ligand in the complexes.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Zenodo (CERN European Organization for Nuclear Research)
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
