Abstract
Reaction of [Os 3(CO) 10(MeCN) 2] with an equimolar proportion of 2-(benzylthio)-benzaldehyde ( 1) gives three new compounds: two yellow isomers of [Os 3(CO) 10(μ-H)(C 14H 11OS)] ( 2a and 2b) and an orange crystalline compound [Os 3(CO) 9(μ-H)C 14H 11OS)] ( 3). The molecular structures of 2b and 3 are presented. Two different kinds of bonding mode of the ligand were observed, bidentate through S and C(O) in 2 and terdentate through S, C(O) and O in 3.
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