Abstract
Four bis( N-adamantyldithiocarbamato)metal(II) complexes [M(S 2CNHC 10H 15) 2] (M = Ni, Zn, Cd, and Hg) were prepared by metathesis of the corresponding potassium salt, K[S 2CNHC 10H 15]. Characterization of the prepared complexes shown that the presence of only one band in the region 1000 cm −1 in IR spectra can be attributed to a completely symmetrical bonding of the dithiocarbamate ligand, acting in a symmetrical bidentate mode. Also the short thioureide C–N distance in X-ray analysis of Ni complex confirm the delocalization of the π electrons over the S 2CN moiety and strong double bond character.
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