Abstract
The BaLaCuSbO(6) double perovskite has been successfully synthesized by solid state reaction under an air atmosphere. Its structure was refined using powder neutron diffraction in the monoclinic space group I2/m with a 4% antisite disorder on the B cations. Magnetic measurements give signs of 2D-antiferromagnetic behaviour with TN around 64 K. The Jahn-Teller distortion produced by Cu(2+) ions favours a crystallographic tetragonal distortion and consequently the in-plane super-superexchange antiferromagnetic interactions, J(90°), are favoured over the in-plane J(180°) antiferromagnetic exchange interactions. Both, J and J' magnetic interactions have been evaluated according to a Heisenberg antiferromagnetic rectangular model using an approximation to Curie's law in powers of J/T, being |J| around 10 times stronger than |J'|.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
