Abstract
Nano flowers of a new polymeric lead(II) complex containing the azide anions, [Pb(baea)(N3)·(N3)]n (“baea” is the abbreviation of bis(2-aminoethyl)amine), has been synthesized by a sonochemical method. The new nano-structure was characterized by transmission electron microscopy, scanning electron microscopy, X-ray powder diffraction, elemental analyses, and IR spectroscopy. Single crystalline material was obtained using a heat gradient applied to a solution of the reagents. Single-crystal X-ray diffraction analyses show that the coordination number for PbII ions is five, PbN5 and hold hemidirected coordination geometry. To the best of our knowledge, the 1D coordination polymer interact with each other via supramolecular and weak Pb···N interactions to create 2D supramolecular frameworks.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callSimilar Papers
More From: Journal of Inorganic and Organometallic Polymers and Materials
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
