Synthesis and characterization of tetraethylene pentamine functionalized MIL-101(Cr) for removal of metals from water.

Abstract

Metal contamination in water is a worldwide persistent problem. We developed a nano-adsorbent, TEPA-MIL-101(Cr) that exhibits effective removal of heavy metals from real water samples. MIL-101(Cr) was synthesized under solvo-thermal condition. Then MIL-101(Cr) was dehydrated and degassed at high temperature under vacuum to generate the coordinately unsaturated sites which are used for tetraethylene pentamine (TEPA) grafting. The structures, morphologies, and compositions of the sorbents have been characterized. Langmuir and Freundlich isotherm models were applied for describing the adsorption process onto TEPA-MIL-101(Cr). The successful grafting of TEPA on MIL-101(Cr) was verified by Fourier transform infrared. The results of X-ray diffraction, scanning electron microscopy, and CHN analysis show that the structure of TEPA-MIL-101(Cr) retains the original structure of MIL-101(Cr). Thermogravimetric analysis indicates thermo-stability of the adsorbent up to 300 °C. Optimal conditions for adsorption were determined as pH = 6.5 and contact time = 1h. The adsorption capacities of TEPA-MIL-101(Cr) for Pb(II), Cu(II), Cd(II), and Co(II) from aqueous samples were 227.5, 217.7, 221.4, and 215.6mg/g respectively, which is on average more than 8 times that of MIL-101(Cr). Analysis of Langmuir and Freundlich models for describing the adsorption isotherms of TEPA-MIL-101(Cr) reveals that the metal ions were absorbed onto TEPA-MIL-101(Cr) by a favorable physical absorption process. TEPA-MIL-101(Cr) was synthesized successfully by a simple, and cost-effective method. The removal efficiency of TEPA-MIL-101(Cr) for the metal ions achieved more than 95 % in real water samples, which in addition to its thermal stability character make it a promising candidate for water treatment purposes.