Abstract
Five binuclear transition metal(II) complexes, [Mn 2L(μ-Cl)Cl 2], [Fe 2L(μ-Cl)Cl 2], [Co 2L(μ-Cl)Cl 2], [Ni 2L(μ-Cl)Cl 2(H 2O) 2O(H 2O) 2 and [Zn 2L(μ-Cl)Cl 2], were synthesized, where HL is the binucleating ligand 2,6-diformyl-4-methylphenoldi(benzoylhydrazone). Based on the IR spectra, elemental analyses, conductivity measurements and thermal analysis, these complexes are proposed to have an endogenous phenoxide bridge and an exogenous chloride bridge. The ligand field parameters of the nickel(II) complex were obtained from near-IR spectra. The variable magnetic susceptibility (4–300 K) data of the manganese(II), iron(II), cobalt(II) and nickel(II) complexes indicated that the magnetic interactions between metal ions were very weak.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
