Abstract
The synthesis and characterization of RuTp complexes containing the chelating ligands N,N′-bis(phenylmethylene)-1,2-ethylenediamine (NN), 2-pyridinethiol (NS), N,N-bis-(2-(dimethylamino)ethyl)-N′,N′-dimethyl-1,2-ethanediamine) (N-crab), acetylacetonate (acac), and tetramethylethylenediamine (tmeda) is described. While with NN, N-crab, acac, and tmeda mononuclear complexes are formed, a dimeric species is obtained with NS. X-ray structures of some complexes are given. The complexes featuring NN, acac, and tmeda react readily with terminal acetylenes to give vinylidene complexes.
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