Synthesis and characterization of rare-earth metal guanidinates stabilized by amine-bridged bis(phenolate) ligands and their application in the controlled polymerization of rac-lactide and rac-β-butyrolactone

Abstract

Eight rare-earth metal guanidinates supported by a versatile family of bridged bis(phenolate) ligands were synthesized, and their application in initiating stereoselective ROP of rac-lactide and rac-β-butyrolactone were investigated and compared.