Abstract
Praseodymium doped Bi2Sn2O7(BSO), as a visible-light responsive photocatalyst, was prepared by a hydrothermal method with different dopant contents. The as-prepared photocatalysts were investigated by X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), N2adsorption-desorption isotherm, X-ray photoelectron spectroscopy analysis (XPS), and UV-Vis diffuse reflectance spectroscopy (DRS). The photocatalytic activity of prepared catalysts was evaluated by the degradation of Rhodamine Bextra (RhB) and 2,4-dichlorophenol (2,4-DCP) in aqueous solution under visible light irradiation. It was found that Pr doping inhibited the growth of crystalline size and the as-prepared materials were small in size (10–20 nm). In our experiments, Pr-doped BSO samples exhibited enhanced visible-light photocatalytic activity compared to the undoped BSO, and the optimal dopant amount of Pr was 1.0 mol% for the best photocatalytic activity. On the basis of the calculated PL spectra, the mechanism of enhanced photocatalytic activity has been discussed.
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