Synthesis and characterization of porous tree gum grafted copolymer derived from Prunus cerasifera gum polysaccharide.

Abstract

Porous grafted copolymer with excellent thermal stability and swelling capacity was synthesized from water soluble Prunus cerasifera gum polysaccharide (PG) and acrylamide (AM). The monosaccharide compositions and the structure of Prunus cerasifera tree gum were detected by a high-performance anion exchange chromatography (HPAEC) system and 1H NMR and 13C NMR, and the obtained PG-AM copolymer was characterized by Fourier transform infrared (FT-IR), scanning electron microscope (SEM), thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC), respectively. The results indicated that the water soluble polysaccharides obtained from Prunus cerasifera tree gum were mainly composed of l-arabinose (39.78%) and d-galactose (40.59%) with minor amount of xylose, mannose and uronic acids. The maximum percent and the grafting efficiency of grafting acrylamide (AM) onto PG to form PG-AM were obtained by copolymerization between polysaccharide and 3 times (weight) acrylamide with 3 mmol/L potassium persulfate initiator at 50 °C for 1 h. In addition, lots of isolated and conjoint pores were observed in the prepared PG-AM materials, with a diameters distribution between 2 and 10 μm. Compared with PG, the synthesized copolymer PG-AM showed an excellent performance in thermal stability and swelling capacity. The detailed structural characteristic together with excellent thermal stability and swelling properties will benefit efficient utilization of the synthesized copolymer as a precursor for preparation of large-scale environmentally friendly advanced materials with various potential applications.