Abstract
AbstractWe have studied the influence of surfactant nature and concentration, and monomer concentration on the synthesis of poly(methyl methacrylate) (PMMA) using high-frequency ultrasound. Polymerization was carried out via free radicals from aqueous solutions with several concentrations of an anionic (sodium lauryl sulfate, SLS) or a cationic surfactant (cetyltrimethylammonium bromide, CTAB) and different concentrations of the insoluble monomer methyl methacrylate (MMA) as the dispersed phase. The polymer particles obtained were characterized by FTIR, differential scanning calorimetry (DSC) and scanning electron microscopy (SEM). The IR spectra show the presence of the characteristic absorption bands for PMMA when SLS was used. When CTAB was employed, for all surfactant concentrations and high monomer concentration (14% v/v), PMMA was obtained. However, bands of the surfactant were present for lower monomer concentrations. The glass transition temperature measured by DSC was in the range 106 - 126°C characteristic of PMMA. Maximum conversion was obtained when the anionic surfactant was employed. SEM studies show the formation of sub-micrometric PMMA latex spheres with average particle size from 65 to 100 nm when the anionic surfactant was used and 65 nm - 0.3 μm for the cationic surfactant.
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