Synthesis and Characterization of Polymeric (PMMA-PVA) Hybrid Thin Films Doped with TiO2 Nanoparticles Using Dip-Coating Technique

Ahmad Alsaad,Ahmad Ahmad,Shatha Al Fawares,Issam A Qattan,Qais Al-Bataineh,Abdul Raouf Al Dairy

doi:10.3390/cryst11020099

Abstract

We report the synthesis of hybrid thin films based on Poly(MethylMethAcrylate) (PMMA) and Poly(VinylAlcohol) (PVA), doped with different concentrations of titanium dioxide nanoparticles (TiO2 NPs). As-prepared thin films of (PMMA-PVA) doped by TiO2 NPs (wt.% = 2%, 4%, 8%, and 16%) are deposited on glass substrate. Transmittance (T%), reflectance (R%), absorption coefficient (α), optical constants (n and k), and optical dielectric functions (ε1 and ε2) are deduced using the experimental transmittance and reflectance spectra. Furthermore, a combination of classical models such as Tauc, Urbach, Spitzer-Fan, and Drude models are applied to calculate the optical and optoelectronic parameters and the energy gaps of the prepared nanocomposite thin films. The optical bandgap energy of PMMA-PVA thin film is found to be 4.101 eV. Incorporation of TiO2 NPs into PMMA-PVA polymeric thin films leads to a decrease in the optical bandgap and thus bandgap engineering is possible. Fourier-transform infrared spectroscopy (FTIR) transmittance spectra of thin films are measured and interpreted to identify the vibrational modes. To elucidate the chemical stability, thermogravimetric (TGA) curves are measured. We found that (PMMA-PVA)/TiO2 NPs polymeric thin films are thermally stable below 110 °C enable them to be attractive for a wide range of optical and optoelectronic applications.

Highlights

Hybrid Polymeric nanocomposite thin films have gained much attention owing to their unusual physical, chemical, and optical properties
A UV–Vis spectrophotometer is employed to investigate the optical properties of the (PMMA-PVA)/TiO2 nanocomposite thin films with various contents of TiO2 -NPs
The Fourier-transform infrared spectroscopy (FTIR) results reveal some sorts of interaction between the constituents of nanocomposite thin films as indicated by the induced changes in the vibration modes and the band position

Summary

Introduction

Hybrid Polymeric nanocomposite thin films have gained much attention owing to their unusual physical, chemical, and optical properties. The discrepancy in the values of refractive index between the polymeric matrix and the semiconductor host results in Fresnel losses. This could be compensated by using polymeric material of a high refractive index [2]. The advancement of polymeric composite thin films is basically determined by the selection of ionic fillers and optimum filler loads. For high refractive index-polymer to operate effectively, it should often exhibit higher optical transparency [3,4,5]. High refractive index polymers are key candidates for organic light emitting diode devices [7], lithography [8], advanced display devices [9], and micro lens components [10]

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