Abstract
Silver nanoparticles were synthesized by chemical reduction method. The Ag nanoparticles (AgNP) were characterized using UV-Vis spectroscopy which shows an absorption band at 420 nm confirming the formation of nanoparticles. For any practical application of the silver nanoparticles it is necessary to stabilize it which can be done by making a composite. In the present studies three polymers were chosen such that AgNP could be put to some practical use. Polyvinyl Alcohol (PVA), Polypyrrole (Ppy) and Carboxymethyl cellulose (CMC) are important for use in textiles, electronics and food/drug technologies respectively. Polymeric composites of PVA, PPy, and CMC were prepared by mixing the aqueous solutions of the respective polymers and the colloidal suspension of preformed silver nanoparticles. Various compositions containing 1% to 5% of Ag nanoparticles were prepared. Thin films of these composites were characterized by UV-Vis spectroscopy, X-ray diffraction and Scanning electron microscopy. X-ray diffraction showed the presence of the peaks at 2θ values of 38.1°, 44.2°, 64.4 and 78.2° corresponding to cubic phase of silver metal. SEM photographs revealed the presence of Ag nanoparticles of sizes varying from 40 to 80 nm. The electrical conductivity of these materials was studied using the four probe method. The conductivity was found to increase from 10–6 for control samples to 10–3 S/cm after the formation of the nanocomposites.
Highlights
Nanotechnology has assumed a great importance in recent years on account of its possible applications in several areas such as electronics, pharmacy, computers, catalysis, biotechnology etc. [1]
Polymeric composites of Polyvinyl Alcohol (PVA), PPy, and Carboxymethyl cellulose (CMC) were prepared by mixing the aqueous solutions of the respective polymers and the colloidal suspension of pre-formed silver nanoparticles
Thin films of these composites were characterized by UV-Vis spectroscopy, X-ray diffraction and Scanning electron microscopy
Summary
Nanotechnology has assumed a great importance in recent years on account of its possible applications in several areas such as electronics, pharmacy, computers, catalysis, biotechnology etc. [1]. Metallic nanoparticles of Ag, Au, Cu and Zn have been the focus of specific interest due to its unique properties such as antibacterial, optical bi-stability, photoresponsivity etc In spite of such importance the instability of nanoparticles gives rise to aggregation which deters its use for specific applications. It is important to take into account the possible interaction between the core and shell, so that the unique combination can be understood. The nanocomposites formed were characterized using UV-Vis spectroscopy (UV-Vis), X-ray diffraction (XRD) and Scanning electron Microscopy (SEM) The advantages of these nanocomposites over the control polymer and industrial applications will be reported in a separate communication
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