Synthesis and characterization of poly(1,5-naphthylene vinylene) and its copolymers with poly(2-methoxy-5-(2′-ethylhexyloxy)- p-phenylene vinylene)

Abstract

Poly(1,5-naphthylene vinylene) (PNV) and its copolymers with poly(2-methoxy-5-(2′-ethylhexyloxy)- p-phenylenevinylene) (MEH–PPV) were synthesized via a liquid–solid two-phase reaction. The liquid phase was a tetrahydrofuran (THF) solution of the monomers, 1,4-bis(bromomethyl)-2-methoxy-5-(2-ethylhexyloxy)benzene (MOEHODCX) and 1,5-bis(bromomethyl) naphthalene (DBMN), and contained a certain amount of tetrabutylammonium bromide (TBAB) as a phase transfer catalyst. The solid phase was potassium hydroxide particles with diameters smaller than 2 mm. The structures of the polymers were studied by infrared and Raman spectroscopies. The solutions of the copolymers emitted green light. The UV–vis and photoluminescence spectral bands of the copolymers showed blue shifts with the increase in their PNV contents. A polymer light-emitting diode was fabricated with the copolymer prepared by copolymerization MOEHODCX and DBMN with feeding molar ratio of 1:1, and its luminescence efficiency was measured to be 0.069.