Abstract
A series of new platinum complexes of the type [Pt(3-mepip) 2X] (where 3-mepip=3-methylpiperidine, and X=dichloro, sulfato, oxalato, malonato, methylmalonato, dimethylmalonato, tartronato, 1,1-cyclopropanedicarboxylato (CPDCA) or 1,1-cyclobutanedicarboxylato (CBDCA) ligand) were synthesized and characterized by elemental analysis, IR spectroscopy and 195Pt nuclear magnetic resonance spectroscopy. The crystal structure of [Pt(3-mepip) 2(malonato)]·0.79H 2O was determined by single crystal X-ray diffraction. In this complex platinum has slightly distorted square planar geometry with two adjacent corners being occupied by two nitrogens of 3-methylpiperidine, whereas the remaining two adjacent corners are occupied by two oxygen atoms of the malonato group. An intricate network of intermolecular hydrogen bonds holds the crystal lattice together. In the other complexes, 3-mepip acts as non-leaving ligands, whereas the carboxylato ligands act as leaving groups.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
