Abstract
AbstractPoly(ε‐caprolactone) (PCL) with a pendent coumarin group was prepared by solution polycondensation from 7‐(3,5‐dicarboxyphenyl) carbonylmethoxycoumarin dichloride and α, ω‐dihydroxy terminated poly(ε‐caprolactone) with molecular weights of 1250, 3000, and 10,000 g/mol. These photosensitive polymers underwent a rapid reversible photocrosslinking upon exposure to irradiation with alternating wavelengths (>280/254 nm) without a photoinitiator. The thermal and mechanical properties of the photocrosslinked films were examined by means of differential scanning calorimetry and stress–strain measurements. The crosslinked films exhibited elastic properties above the melting temperature of the PCL segment along with significant decrease in the ultimate tensile strength and Young's modulus. Shape‐memory properties such as strain fixity ratio (Rf) and strain recovery ratio (Rr) were determined by means of a cyclic thermomechanical tensile experiments under varying maximum strains (εm = 100, 300, and 500%). The crosslinked ICM/PCL‐3000 and ‐10,000 films exhibited the excellent shape‐memory properties in which both Rf and Rr values were 88–100% for tensile strain of 100–500%; after the deformation, the films recovered their permanent shapes instantaneously. In vitro degradation was performed in a phosphate buffer saline (pH 7.2) at 37 °C with or without the presence of Pseudomonas cepacia lipase. The presence of the pendent coumarin group and the crosslinking of the polymers pronouncedly decreased the degradation rate. The crosslinked biodegradable PCL showing a good shape‐memory property is promising as a new material for biomedical applications. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 2422–2433, 2009
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