Synthesis and characterization of novel hyperbranched alkyd and isocyanate trimer based high solid polyurethane coatings

Abstract

In the present work, hyperbranched urethane alkyd high solid coatings were formulated by mixing hyperbranched alkyd and isocyanate trimer. Initially, a second generation hyperbranched polyol (HBP) was synthesized using dipentaerythritol (DPE) as a core material and 2,2-bis(methylol)propionic acid (BMPA) as a chain extender. This was reacted with varying concentrations of linseed oil fatty acid (LOFA) to make a series of hyperbranched alkyd (HBA) resins. Viscosity and volume solid of the HBA resins were measured. The resins were characterized by Fourier transform infrared (FTIR), and 13C Nuclear magnetic resonance (13C NMR) spectroscopic techniques. The hyperbranched alkyd resins containing varying amount unreacted hydroxyl groups were cured with hexamethylene diisocyanate (HDI) trimer (Desmodur N 3390) depending on their NCO: OH ratio to make hyperbranched urethane alkyd coatings. A series of such coatings were made by mixing HBA/isocyanate trimer (Desmodur N 3390) ratio with respect to the hydroxyl group present on the HBA. The performance of the coated specimens was evaluated by various techniques such as pull-off adhesion strength, tensile strength, abrasion resistance, scratch resistance, flexibility, and impact resistance tests. The weathering properties of the coated specimens were evaluated by UV-Weatherometer. Corrosion resistance of the coated specimens was evaluated by electrochemical impedance spectroscopy (EIS), salt spray, seawater immersion and humidity tests. It was observed that, there exists an optimum coating composition in terms of NCO: OH (HBA: Desmodur N 3390) ratio which showed excellent enhancement in terms of the mechanical, weathering and corrosion resistance properties than remaining coating compositions.