Abstract
AbstractThe synthesis and characterization of two N‐heterocyclic carbene (NHC) complexes of titanium (IPr)Ti(NMe2)2Cl2 (1) [IPr = 1,3‐bis(2,6‐diisopropylphenyl)imidazol‐2‐ylidene] and (IPr)2TiCl3 (2) are described. Reactions of one and two equivalents of IPr with Ti(NMe2)2Cl2 and TiCl3(thf)3 yield the mono‐NHC titanium(IV) complex 1 and the bis‐NHC titanium(III) complex 2, respectively. They feature distorted trigonal bipyramidal geometries. Short intramolecular Cl···CNHC contacts are observed in the X‐ray single‐crystal structures of 1 and 2.
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