Abstract
AbstractThe synthesis of side‐chain liquid‐crystalline oligocyclosiloxanes containing methyleneoxymethylene spacers, two different mesogenic cores (including biphenyl phenyl carboxylate or biphenyl fluorophenyl carboxylate groups) and chiral tails is presented. Differential scanning calorimetry, optical polarizing microscopy and X‐ray diffraction measurements reveal liquid‐crystalline properties for all of the synthesized monomers and oligomers. All cyclic oligosiloxanes exhibit enantiotropic smectic A and chiral smectic C phases. The mesogenic properties of the cyclic oligomers and side‐chain liquid‐crystalline precursor are discussed. Copyright © 2005 Society of Chemical Industry
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