Abstract

Naphthalene end‐capped triethylsilylethynyl anthradithiophene was synthesized by a Suzuki coupling reaction. The obtained compound had good solubility due to its bulky triethylsilylethynyl groups although the extended π‐conjugated backbone structure. The thermal stability of the new material was analyzed by thermogravimetry analysis and differential scanning calorimeter thermograms. The optical and electrochemical properties were examined. A thin film of compound was fabricated by spin‐coating and exhibited p‐channel organic thin film transistors (OTFTs) transport with hole mobility of 4 × 10−4 cm2/Vs.

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