Abstract
Nanocrystalline CeO 2 particles were firstly prepared by two-stage non-isothermal precipitation, i.e. precipitating at 70 °C and aging at another temperature. Experimental results showed that the intermediates at the end of precipitation stage were needle-like mixtures of Ce 3+–Ce 4+ compounds. The subsequent aging temperature played an important role on the shape and size of final products. As the aging temperature suddenly reduced to 0 °C, the resultant particles retained their original needle-like structure via the topotactic mechanism, which cannot be obtained by isothermal precipitation. As raising the aging temperature above 50 °C, the products were hexagonal and grown up with increasing temperature via the dissolution–recrystallization mechanism. Moreover, all products were cubic-fluorite structured CeO 2 with negligible Ce 3+ content. As compared to the nanohexagons (aged at 90 °C), the nanoneedles (aged at 0 °C) exhibited an unordinary red shift in the UV absorption and possessed a smaller bandgap energy.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
