Synthesis and Characterization of Na2/3[Fe1/2Mn1/2]O2 Cathode Material for Sodium Ion Batteries

Abstract

<p><strong>Abstract. </strong>Recently,<strong> </strong>Na<sub>2/3</sub>[Fe<sub>1/2</sub>Mn<sub>1/2</sub>]O<sub>2</sub> has received attention as a potential candidate material for cathode sodium-ion batteries. However, this material was synthesized by a solid-state process, resulting in larger particle size and nonuniform morphology. The larger particle size will sluggish the Na ion diffusion. Here we report the synthesis of Na<sub>2/3</sub>[Fe<sub>1/2</sub>Mn<sub>1/2</sub>]O<sub>2</sub> using a simple sol-gel process. The X-ray diffraction revealed that the sample was identified as Na<sub>2/3</sub>[Fe<sub>1/2</sub>Mn<sub>1/2</sub>]O<sub>2</sub> with a hexagonal crystal structure. However, the impurities are formed at diffraction angles of 36.28°, 45.03°, and 51.23°. Calcination temperature affects the formation of the crystal phase, grain growth, morphology, and particle size. Our findings provide valuable insight into the development of Na<sub>2/3</sub>[Fe<sub>1/2</sub>Mn<sub>1/2</sub>]O<sub>2</sub> material with desirable properties.</p><p> </p><p><strong>Keywords:</strong></p><p>Sol-Gel, Solid State, Grain Growth, Calcination, Na<sub>2/3</sub>[Fe<sub>1/2</sub>Mn<sub>1/2</sub>]O<sub>2</sub></p><p> </p>