Synthesis and characterization of MWCNT-covered stainless steel mesh with Janus-type wetting properties

Abstract

Various multi-step methods to fabricate Janus membranes have been reported in literature. However, no article so far reports the durability of the Janus membranes when exposed to liquids. We report on a novel method to fabricate a Janus-type multi-walled carbon nanotubes (MWCNT)-covered stainless steel (SS) mesh, which retains dual-wetting properties even after exposure to water for 540 d. The MWCNTs are grown directly on stainless steel mesh coupons by chemical vapor deposition using acetylene as the carbon source, and are then plasma functionalized using an ammonia-ethylene gas mixture to achieve dual-wettability. We found by x-ray photoelectron spectroscopy that the MWCNTs on the top face of the novel Janus MWCNT-SS mesh, which was directly exposed to the plasma, are coated by a plasma polymer rich in nitrogen-containing functional groups, while the MWCNTs on the bottom face are almost devoid of the plasma polymer coating. Atomic force microscopy studies confirmed that the surface roughness of the bottom face of the mesh is lower than the minimum roughness that allows the capillary ingress of water to sustain its superhydrophobic behavior. In addition, scanning electron microscopy studies also confirmed that the MWCNTs on the bottom face of the treated MWCNT mesh are vertically aligned compared to the MWCNTs on the top face of the mesh. The vertically aligned dense MWCNT forest on the bottom face attributes to its superhydrophobic nature.