Abstract
A new mononuclear complex was successfully synthesized on the basis of a Schiff-base ligand L=1,2-phenylendiamine-N,N′-bis(3-tert-butyl-5-(4-pyridyl)salicylidene) and CuCl2. Its structure was characterized by single-crystal X-ray diffraction, IR spectroscopy, thermogravimetric analysis (TGA) and powder X-ray diffraction. The complex has a remarkable activity for photodegradation of organic dyes under visible-light illumination. Moreover, the complex showed optical property: a fluorescence quenching phenomenon was observed at 518nm when using a 350nm excitation light to stimulate the samples.
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