Synthesis and characterization of MoVTeCeO catalysts and their catalytic performance for selective oxidation of isobutane and isobutylene

Abstract

A series of Mo-based catalysts (MoVCeO, MoTeCeO, MoVTeO, and MoVTeCeO mixed metal oxides) were prepared and tested for the oxidation of isobutane and isobutylene. Characterization results (XRD, FTIR, TPR, XPS, and BET) showed that their structure and properties depend on the composition of the calcined samples. Catalytic tests showed that molybdenum may be the key element for the activation of isobutane, whereas the selective oxidation of isobutylene to methacrolein (MAL) might proceed mainly on the surface of the TeMo-containing crystalline phase. In addition, Te4+ may favor the formation of methacrylic acid (MAA). The incorporation of Ce ions may modify the redox process of the catalysts and thus influence the catalytic behaviors for the selective oxidation of isobutane. Thus, the selectivities and yields of MAL and MAA can be increased over these specially designed catalysts.