Abstract
Two new series of cobaloxime complexes of formulae [Co(Hdmg) 2{(CH 2) n I}(py)] (Hdmg = the monoanion of dimethylglyoxime, py = pyridine and n = 5, 6, 8, 9 or 10) and [Co(Hdmg) 2{(CH 2) 3OC(O)C 6H 4R}(py)] (R = H, o-, m- or o-OCH 3, p-OC 7 H 15 or p-OC 9H 19) have been synthesized and fully characterized. The former series provides versatile precursor species for a wide range of polymethylene homo- and heteronuclear complexes, while the latter series confirms that, under mild conditions, elaboration from an ω-hydroxyl group can be achieved to generate stable metal complexes.
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