Abstract
Iridium complexes of N-alkylphenothiazines have been prepared in MeOH. The polynuclear complexes obtained have been characterized by elemental analyses, magnetic susceptibilities, molar conductivities, thermogravimetric analysis and spectral data. The molecular formulae of the new complexes are as follows: [Ir3(LH)4Cl10]Cl2·xMeOH, where L = chlorpromazine (CP), promethazine (PM) or ethopropazine (EP), and x = 1 for CP and 2 for PM or EP; [Ir(TFH2)2Cl4][IrCl6]·MeOH, where TF = trifluoperazine; and [Ir2(TRH)2Cl11(MeOH)]Cl·MeOH and [Ir4(TRH)3Cl15], where TR = thioridazine. The complexes are diamagnetic in nature. Tentative structures are proposed for the complexes.
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