Synthesis and characterization of high strength and ultraviolet transmitting silicone rubber reinforced by organic solvent‐soluble trimethylsiloxysilicate polymers (MQ and MTQ copolymers)

Abstract

AbstractAdditional‐type liquid silicone rubber (ALSR) has poor mechanical properties, and conventional methods to reinforce it are at the cost of decreasing transparency. Here, vinyl MQ and fluorine‐containing MTQ silicone resins were synthesized by the sol–gel method. Then, high strength and ultraviolet (UV) transmitting ALSR were prepared using MQ and MTQ silicone resins as reinforcing agents, vinyl‐terminated silicone oil, and polydimethylmethylhydrosiloxane as matrix, respectively. The results show that the enhancement effect of MTQ silicone resin on the mechanical properties of ALSR resin is better than that of MQ silicone resin due to the vinyl content of MTQ silicone resin being higher than that of MQ silicone resin. Compared with pure ALSR, the tensile strength, Young's modulus, and Shore hardness of ALSR with 7 wt% MTQ silicone resin are enhanced by 435%, 127%, and 14%, respectively. The thermal stability of ALSR is slightly increased. The modified silicone rubber also has favorable transparency. Additionally, the MTQ/ALSR composites show higher UV transmittance than MQ/ALSR systems owing to the introduction of fluorine element increasing UV transmittance. The high strength and UV transmittance silicone rubber composites were prepared by using a small addition of MTQ silicone resin.