Abstract
AbstractThe germanium(II) and gallium(III) organochlorides containing the C6F5‐substituted β‐diketiminate ligand LGeCl (2) and LGaCl2 (3) (L = HC[(CMe)(NC6F5)]2) were synthesized. Salt elimination reactions of the C6F5‐substituted β‐diketiminato lithium salt with the corresponding germanium(II) and gallium(III) chlorides led to the organochlorides respectively. Compounds 2 and 3 were characterized by spectroscopic and elemental analyses, and 2 was further investigated by single crystal X‐ray structural analysis.
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