Abstract

The monoclinic β-gallium oxide (Ga2O3) was viewed as a potential candidate for power electronics due to its excellent material properties. However, its undoped form makes it highly resistive. The Ga2O3/SnO2 nanostructures were synthesized effectively via the horizontal vapor phase growth (HVPG) technique without the use of a magnetic field. Different concentrations of Ga2O3 and SnO2 were varied to analyze and describe the surface morphology and elemental composition of the samples using the scanning electron microscopy (SEM) and energy-dispersive X-ray (EDX) spectroscopy, respectively. Meanwhile, the polytype of the Ga2O3 was confirmed through the Fourier transform infrared (FTIR) spectroscopy. The current-voltage (I–V) characteristics were established using a Keithley 2450 source meter. The resistivity was determined using the van der Pauw technique. The mobility and carrier concentration was done through the Hall effect measurements at room temperature using a 0.30-Tesla magnet. It was observed that there was an increase in the size of the nanostructures, and more globules appeared after the concentration of SnO2 was increased. It was proven that the drop in the resistivity of Ga2O3 was due to the presence of SnO2. The data gathered were supported by the Raman peak located at 662 cm−1, attributed to the high conductivity of β-Ga2O3. However, the ε-polytype was verified to appear as a result of adding SnO2. All the samples were considered as n-type semiconductors. High mobility, low power loss, and low specific on-resistance were attained by the highest concentration of SnO2. Hence, it was clinched as the optimal n-type Ga2O3/SnO2 concentration and recommended to be a potential substrate for power electronics application.

Highlights

  • Silicon-based technology has been the mainstream in power electronics [1]

  • Is pursuit was an initial investigation on the synthesis of Ga2O3/SnO2 via the horizontal vapor phase growth (HVPG) technique without the application of the magnetic field. e concentration of SnO2 was varied to determine its effect on the surface morphology and electrical attributes of Ga2O3 for potential power electronic applications. e characterizations were performed using scanning electron microscopy (SEM) and energy-dispersive X-ray (EDX), while the polytypes were affirmed through the known peaks of Raman. e infrared (FTIR) spectroscopy. e current-voltage (I–V) curves were uncovered using a two-point probe test and the van der Pauw technique for the electrical resistivity. e Hall effect measurements revealed the carrier concentration and mobility

  • The mass loadings were named as sample A (100 : 0 wt.%) or the asgrown, sample B (99 : 2 wt.%), sample C (98 : 2 wt.%), and sample D (90 :10 wt.%). e samples were poured in fused-silica quartz tubes and sealed under a high-vacuum system, while the pressure was maintained at 10−6 Torr

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Summary

Introduction

Silicon-based technology has been the mainstream in power electronics [1]. its power devices are approaching their physical limitation [2] when operating at extreme voltage, current, power, and temperature environments, allowing other semiconductor materials to dominate large market sectors untouched by Si-based devices [3]. E concentration of SnO2 was varied to determine its effect on the surface morphology and electrical attributes of Ga2O3 for potential power electronic applications. A similar image is noticed in Figure 8(a) and the asgrown sample, which matches the bulk Ga2O3 powder, with size ranging from 190 nm to 1,937 nm and mean size of 662.265 nm.

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