Abstract

AbstractA new tetradentate N‐donor ligand (L) based on 2,11‐diaza[3.3](2,6)pyridinophane with N‐bonded (CF3)2(OH)CCH2 groups is presented, along with the coordination compounds [(L)FeCl2][FeCl4], [(L)MnCl2], [(L)Cu(OAc)2] and [(L)Zn(OTf)(H2O)](OTf) (OAc=acetate; OTf=trifluomethylsulfonate). All metal complexes possess a distorted octahedral geometry around the metal center.

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