Abstract
The chelating aluminum complex [{3,5-N-tBu2pz-N′−CH=C(SiMe3)}AlR1R2] [R1 = R2 = Me (2); R1 = R2 = H (3); R1 = R2 = I (4)] was prepared in modest yield from an organoaluminum dichloride precursor [{3,5-N-tBu2pz-N′−CH=C(SiMe3)}AlCl2] (1). Compounds 2 and 3 were obtained from the reaction of 1 with MeLi in Et2O or with LiAlH4 in THF, respectively. Reaction of 2 or 3 with I2 in toluene gave 4. In addition, the reaction of 1 with two equivalents of water yielded the hydrolyzed product H[3,5-N-tBu2pz-N′−CH=C(SiMe3)] (5). All compounds were characterized by elemental analysis, NMR spectroscopy, and mass spectrometry. The X-ray structure analysis shows that complex 2 exhibits one fused five-membered AlC2N2 ring and one pyrazolato ring system. (© Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002)
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
