Abstract
Abstract[Cp2Ln(μ‐SR)]2 was reacted with Ph2CCO to yield ketene mono‐insertion products [Cp2Ln(μ‐η1:η2‐OC(SR)=CPh2)]2 [R=Bn, Ln=Yb (1), Er (2), Y (3) and R=Ph, Ln=Yb (4)], indicating that the reactions of organolanthanide thiolates with ketenes are independent of the nature of the thiolate ligand and the ketene as well as the reaction condition. These reactions could provide an efficient method for the synthesis of organolanthanide complexes with the α‐thiolate‐substituted enolate ligand. All these complexes were characterized by elemental analysis and spectroscopic properties and the structure of complex 1 was determined through X‐ray single crystal diffraction analysis.
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